Inorganic Chemistry (Gary L. Miessler) 5th
1. CHFClBr
2. H2C=CClBr
3. HClBrC-ChClBr
4.
5.
6.
7.
8.
풀이:
9. PF5
10. H3CCH3
11. [Co(en)3]3+
12. NH3
13. H2O2
14. 1,5-다이브로모나프탈렌
15. 1,3,5,7-테트라플루오로사이클로옥타테트라엔
9~15 풀이:
16. difluorodiazene
17. B(OH)3, planar
18. H2O
19. PCl3
20. BrF5 (square pyramid)
21. HF, CO, HCN
22. N2H4, which has a gauche conformation
23. P(C6H5)3, which is like a three-bladed propeller distorted out of the planar shape by a lone pair on the P
16~23 풀이:
24. BF3
25. PtCl4 2-
26. Os(C5H5)2 (eclipsed)
27. benzene
28. F2, N2 acetylene (C2H2)
24~28 풀이:
29. H2C“C“CH2, allene
30. Ni(cyclobutadiene) 2 (staggered)
31. Fe(C5H5)2 (staggered)
32. 3Ru(NH2CH2CH2NH2)3 4 2+ (treating the NH2CH2CH2NH2 group as a planar ring)
29~32 풀이:
p.102 Example 4.2
Determine the point groups of the following molecules from Figures 3.13 and 3.16
1) XeF4
2) SF4
3) IOF3
풀이:
